中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 25 No. 4 April 2015 |
（1. School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;
2. Key Laboratory for Advanced Materials Processing Technology,
Ministry of Education, Tsinghua University, Beijing 100084, China）
Abstract:The evolution of nanoporous structure with dealloying condition was investigated, thus, the mechanism of porous structure evolution was uncovered. The Gasar Cu-Mn alloy was dealloyed by room and elevated temperature chemical corrosion, low and high current level electrochemical corrosion, four types of porous structures, including uneven corrosion pits, hybrid porous, haystack type and bicontinuous model were prepared by chemically and electrochemically dealloying the porous Cu-34.6%Mn alloy made by the Gasar process. Then, the surface diffusion coefficient (DS) and the diffusion frequency (kD) of Cu atom, as well as the dissolution frequency (kE) of Mn atom were calculated with dealloying condition. The dealloyed morphologies for room temperature chemical corrosion and low current level electrochemical corrosion were similar due to the same DS. While the dealloyed structures changed from bulk hybrid porous structure to bicontinuous porous film with decreasing kD/kE.
Key words: Gasar process; dealloying; hybrid porous; nanoporous structure
