(湘潭大学 化学学院 环境友好化学与应用教育部重点实验室，湘潭 411105)
摘 要: 用溶剂热法制备金属有机骨架化合物(MOF-5，对苯二甲酸-锌配位化合物)，将糠醇引入MOF-5的孔道中得到碳前驱体，炭化处理后，用14.5 mol/L HNO3进一步活化，得到新型多孔炭材料。用红外光谱、扫描电镜、X射线衍射和N2吸附等温线等对其进行测试和表征。结果表明：经硝酸处理后的多孔炭材料表面含氧官能团明显增加。由于多孔炭材料具有较高的双电层电容，而含氧官能团能提高材料的氧化还原赝电容，因此材料具有优良的电化学性能。循环伏安测试表明，在6.0 mol/L KOH电解液中扫描速度为5 mV/s时，多孔炭材料的比电容高达243.3 F/g，组装成超级电容器经5 000次循环后比电容仍高达74 F/g。
关键字: 多孔炭材料；Zn4O(OOCC6H4COO)3 (MOF-5)；糠醇；超级电容器
（Key Laboratory of Environmentally Friendly Chemistry and Applications, Ministry of Education,
School of Chemistry, Xiangtan University, Xiangtan 411105, China）
Abstract:The carbon precursor was prepared by infiltrating the furfuryl alcohol into pores of metal-organic framework (MOF-5, Zn4O(BDC)3, BDC=1,4 benzendicarboxylate), which was synthesized by solvothermal method. With the direct carbonization and further activation treatment with 14.5 mol/L HNO3, a new porous carbon material was obtained. Infrared spectrum (IR), scanning electron microscope (SEM), X-ray diffraction (XRD) and N2 adsorption/desorption isotherm were utilized to characterize the as-prepared new porous carbon material. The results show that the oxygen-enriched functional groups on the surface of the new porous carbon material obviously increase after HNO3 activation. Due to the combination of electric double-layer capacitance of the porous carbon material and pseudo-capacitance of the oxygen-enriched functional groups, the as-prepared new porous material shows an excellent electrochemical performance. The results based on cyclic voltammetry test demonstrate that the specific capacitance is as high as 243.3 F/g at a scanning rate of 5 mV/s in 6.0 mol/L KOH electrolyte. Furthermore, the specific capacitance of the supercapacitor using this new porous carbon as the electrode active material still keeps at 74 F/g after 5 000 cycles.
Key words: porous carbon materials; Zn4O(OOCC6H4COO)3 (MOF-5); furfuryl alcohol; supercapacitor
