Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第6卷    第4期    总第21期    1996年12月

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文章编号:(1996)04-153-3
氮化硅陶瓷烧结过程中的致密化与相变
杨海涛1,汤宇凌1,徐润泽2,黄培云2

(1.武汉工业大学新材料研究所,武汉430070;
2.中南工业大学粉末冶金研究所,长沙410083
)

摘 要: 讨论了Si3N4-MgO-CeO2陶瓷常压烧结过程中的致密化与相变。指出:对于Si3N4-MgO-CeO2陶瓷,在1500~1550℃为快速致密化阶段,在1 550℃致密化过程已接近完成,α-Si3N4→β-Si3N4的相转变过程滞后于致密化过程,在1550~1600℃为β相转变百分数急剧增加阶段,在1600℃,α→β相变接近完成。α→β相变与其致密化并无直接、必然的关系。

 

关键字: 氮化硅 致密化 相变

DENSIFICATION AND PHASE TRANSFORMATION DURING
SINTERING OF Si3N4-MgO-CeO2CERAMICS
Yang Haitao1, Tang Yulin1, Xu Runze2, Huang Peiyun2

1.National Lab for Hybrid Materials, Wuhan University of Technology, Wuhan 430070
Research Institute ofPowder Metallurgy,
2.Central South University of Technology, Changsha 410083

Abstract:The effect of pressureless sintering on the densification and phase transformation of Si3N4-MgO-CeO2 ceramics was studied. For the Si3N4-MgO-CeO2ceramics, the densification process took place rapidly from 1500 to 1550℃and nearly completed at 1550℃; the phase transformation fromα-Si3N4toβ-Si3N4 took place rapidly from 1550 to 1600℃and nearly completed at 1600℃. The phase transformation process is behind the densification process and does not necessarily promote the densification of the Si3N4-MgO-CeO2ceramics.

 

Key words: Si3N4 densification phase transformation

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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