Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第9卷    第3期    总第32期    1999年9月

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文章编号:1004-0609(1999)03-0620-04
含锂盐阳极中Li2CO3在铝电解温度下的存在形式
孙     挺1 邱竹贤2    张庆功2   李    冰2   朱旺喜3

(1. 东北大学理学院; 2. 材料与冶金学院,沈阳 110006;3. 北京矿冶研究总院,北京 100044)

摘 要: 通过对烧结后含锂盐炭阳极糊的红外光谱、X 射线衍射和热分析研究表明,在铝电解的温度和条件下,炭阳极中的Li2CO3仅少量分解且仍是其主要存在形式。由于碳的存在使Li2CO3的分解率大大降低,使其分解温度大大高于文献报道的Li2CO3的热分解温度。

 

关键字: Li2CO3;热分解; 铝电解; 阳极

Existence form of Li2CO3 in anodic paste in Soderbeg cell
Sun Ting1, Qiu Zhuxian2, Zhang Qinggong2, Li Bing2, Zhu Wangxi3

1. School of Sciences, Northeastern University, Northeastern University, Shenyang 110006, P.R.China
2. School of Materials Sciences and Metallurgy,  Northeastern University, Shenyang 110006, P.R.China;
3. Beijing General Research Institute of Mining and Metallurgy, Beijing 10004 4, P.R.China

Abstract:The samples of baked anodic paste adding Li2CO3 were studied by infrared and X-ray diffraction. It was shown that Li2CO3 in the baked anode is decomposed slightly in the condition of aluminum electrolysis in Soderberg cell. But the major form of lithium is still Li2CO3. Due to the existence of carbon, the decomposition of Li2CO3 is decreased greatly.

 

Key words: Li2CO3; thermal decomposition; aluminum electrolysis; anode

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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