Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第13卷    第4期    总第55期    2003年8月

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文章编号:1004-0609(2003)04-0996-05
碳纳米管/镍基复合镀层的腐蚀行为
张 刚, 李绍禄, 陈小华, 王健雄, 陈传盛, 易国军, 孙心瑗

(湖南大学 材料科学与工程学院, 长沙 410082)

摘 要: 采用复合沉积方法在普通碳钢基底上沉积碳纳米管/镍基复合镀层。 用腐蚀实验、 电化学方法研究了复合镀层在3.5%NaCl溶液中的耐腐蚀性能, 并讨论了其耐腐蚀机理, 对普通碳钢和纯镍镀层也进行了比较研究。 结果表明: 碳纳米管的加入显著提高了复合镀层的耐腐蚀性能;耐腐蚀的原因在于碳纳米管的复合镀层更加致密, 隔离了腐蚀介质, 并阻止了蚀坑的增大, 同时, 碳纳米管促进了镍的纯化, 从而提高镀层的耐蚀性。

 

关键字: 碳纳米管; 复合镀层; 腐蚀

Corrosion behavior of carbon nanotubes/Ni composite coating
ZHANG Gang, LI Shao-lu, CHEN Xiao-hua, WANG Jian-xiong,
CHEN Chuan-sheng, YI Guo-jun, SUN Xin-yuan

School of Materials Science and Engineering, 
Hunan University, Changsha 410082, China

Abstract:Carbon nanotubes/Ni composite coating was obtained on steel matrix by co-deposition method. The corrosion resistance properties of carbon nanotubes/Ni composite coating in 3.5% NaCl solutions were investigated by mass-loss method and electrochemical corrosion experiment, and its corrosion resistance mechanism was discussed. The corrosion behaviors of nickel coating and Fe were compared with the composite coating. The results show that the corrosion resistance of composite coating is improved significantly by incorporation of carbon nanotubes.

 

Key words: carbon nanotubes; composite coating; corrosion

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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