Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第12卷    第4期    总第49期    2002年8月

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文章编号:1004-0609(2002)04-0739-04
LiCoO2结构及性能与锂离子电池电压特性的关系
李新海,郭永兴,王志兴,彭文杰,郭华军,王红强

(中南大学 冶金科学与工程系,长沙 410083)

摘 要: 采用激光衍射,BET,XRD,SEM等方法,研究了系列LiCoO2正极材料的一些物理化学性能及其与锂离子电池电压特性的关系,并对由3种LiCoO2样品制成的试验电池进行了电压特性和循环寿命的测试,得出了制备有良好电压特性的锂离子电池用LiCoO2正极材料所应具备的性能:XRD谱线中I003/I104的值较大,颗粒分布均匀无团聚,表面光滑平整。

 

关键字: LiCoO2;锂离子电池;电压特性

Relationship between structure and
performances of lithium cobalt oxide
and voltage characteristics of
lithium-ion battery
LI Xin-hai,GUO Yong-xing,WANG Zhi-xing,PENG Wen-jie,
GUO Hua-jun,WANG Hong-qiang

Department of Metallurgical Science and Engineering,
Central South University,Changsha 410083,China

Abstract:Some physical and chemical performances of lithium cobalt oxide cathode material and the relationship between them and lithium-ion battery were studied by using several techniques including laser diffraction, BET, XRD, SEM. The experimental lithium-ion batteries using these LiCoO2 samples were tested to evaluate their voltage characteristics and life-span. It is found that the LiCoO2 cathode material for manufacturing a lithium-ion battery with good voltage characteristics may have performance as follows: very high value of I003/I104 in XRD patterns; even particle distribution without gathering and smooth surface.

 

Key words: lithium cobalt oxide; lithium-ion battery; voltage characteristics

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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