( 同济大学 化学系， 上海 200092)
摘 要: 以蛋膜为模板， 利用其仿生矿化机制和对反应离子的控制传输作用， 制备出了铜族硫化物纳米晶， 直接证明了蛋膜用于纳米材料合成的可行性，为半导体纳米材料的制备提供了一种新的方法。 实验获得的CuS、 Ag2S、 Au2S3纳米晶粒径分别为30、 24和22 nm, 均具有主红外透过、 光致发光等性能， 并在紫外—可见吸收光谱中出现了常规材料所不具备的新的吸收峰。
关键字: 纳米晶； 铜族硫化物； 仿生合成； 模板； 蛋膜
（ Department of Chemistry, Tongji University, Shanghai 200092, China）
Abstract: Utilizing biomineralization mechanism of eggshell membrane and its control over ions transfer, three kinds of nanocrystals of copper group sulphides were synthesized with eggshell membrane as a template. This indicates the feasibility of synthesizing nanomaterials with eggshell membrane and provides a novel template method for the formation of inorganic nanomaterials. The results show that the average diameters of CuS, Ag2S and Au2S3 nanocrystals obtained from the experiment were 30, 24 and 22 nm, respectively; the three kinds of nanocrystals all have some special properties such as fluorescence, none absorb peak in FT-IR, and they also have some new absorb peaks in UV-V is while the bulk materials haven't.
Key words: nanocrystals; copper group sulphide; biomimetic synthesis; template; eggshell membrane
