Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    总第115期    2008年10月

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文章编号:1004-0609(2008)10-1852-06
电流密度对无氰电镀Au凸点生长行为的影响
米青霞,黄明亮,王 来

(大连理工大学 三束材料改性国家重点实验室,材料科学与工程学院,大连 116024)

摘 要:

研究一种以氯金酸钠为主盐的无氰镀金液在80 ℃、镀液pH为8.0时阴极电流密度(J)对Au凸点生长行为的影响。结果表明:J在0.5~2.5 A/dm2范围内逐渐增大时,Au凸点生长速度单调增大;当J=0.5~1.0 A/dm2时,所得Au凸点晶粒细小、表面平整、内部致密;当J=1.5~2.5 A/dm2时,随着J的增大,凸点表面粗糙度逐渐增大,内部致密度逐渐降低;从凸点横截面形貌来看,在J=2.0 A/dm2时出现树枝晶,在J=2.5 A/dm2时树枝晶及晶间间隙已非常明显。确定了该镀液制作Au凸点的最佳电流密度为J=1.0 A/dm2。此时,平均凸点厚度与施镀时间之间存在良好的线性关系。在蒸镀Au种子层并刻蚀有图形的Si基板上得到外形规整且与基板结合良好的Au凸点。

 

关键字: 无氰电镀;镀金;Au凸点;电流密度;生长行为

Effect of current density on growth behavior of Au bumps during non-cyanide electroplating
MI Qing-xia, HUANG Ming-liang, WANG Lai

State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China

Abstract: The effect of current density (J) on the growth behavior of Au bumps in a stable non-cyanide gold electrolyte containing NaAuCl4∙2H2O was investigated under 80 ℃, pH 8.0. While J was in the range of 0.5~2.5 A/dm2, the higher the J was, the faster the Au bumps growth rate was. The results show that when J=0.5~1.0 A/dm2, the Au bumps have fine grains, high density and smooth surface. While J =1.5~2.5 A/dm2, the surface of the Au bumps becomes coarsing with increasing J value, whereas the density of the bumps keeps decreasing. Dendrites are clearly observed when J=2.0 A/dm2, and they become pronounced when J=2.5 A/dm2. Through the experiments, J=1.0 A/dm2 is chosen to electroplate Au bumps, under which a linear relationship exists between the average thickness of Au bumps and the electroplating time. Au bumps with regular shape and high adhesive strength with the Si substrate are obtained.

 

Key words: non-cyanide electroplating; Au electroplating; Au bump; current density; growth behavior

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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