Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第5期    总第98期    2007年5月

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文章编号:1004-0609(2007)05-0795-05
Ce-TiO2/硅藻土的制备、表征及其光催化活性
雷 波,徐悦华,郭来秋,罗海燕

(华南农业大学 理学院,广州 510642)

摘 要:

以硅藻土(KL)为载体,用溶胶凝胶法将铈掺杂二氧化钛包覆在硅藻土上(Ce-TiO2/KL)。采用XRDDRSSEM对其进行表征,以250 W高压汞灯作光源,甲醛作为反应底物表征其光催化活性。结果表明:Ce-TiO2包覆在硅藻土颗粒上,并能在较高的煅烧温度(500 ℃)范围内保持锐钛矿晶体结构;随着铈掺杂含量的提高,J2Ce-TiO2/KL对可见光的吸收明显增强,有利于充分利用太阳光。由此可见,TiO2固定在硅藻土上时,铈掺杂不仅提高了其活性,还导致其激发波长红移,还有利于回收利用。

 

关键字: TiO2;硅藻土;Ce掺杂;TiO2/硅藻土;光催化

Preparation, characterization and photocatalytic activity of Ce-
TiO2/kieselguhr
LEI Bo, XU Yue-hua, GUO Lai-qiu, LUO Hai-yan

College of Science, University of South China Agricultural, Guangzhou 510642, China

Abstract: Ce-TiO2/kieselguhr photocatalysts were prepared by sol-gel method under alkalescent conditions, and characterized by X-ray diffractrometry, scanning electron microscopy and DRS. The photocatalytic degradation of formaldehyde was chosen as a model reaction to evaluate the photocatalytic activities of the composite photocatalysts irradiated by 250 W high-pressure mercury lamp. The results show Ce-TiO2 coating on kieselguhr. The crystalline phase of titanium dioxide is still only anatase in wide range of temperature. The light absorption in visible region increases with increasing Ce-doping content in J2Ce-TiO2/kieselguhr, so it is beneficial to use sun’s ray. When Ce-TiO2 is immobilized on kieselguhr, Ce-doping not only enhances its photocatalytic activity, but also extends its respond wavelength. Ce-TiO2/KL is also easy to be recycled and reused.

 

Key words: TiO2; kieselguhr; Ce doping; TiO2/kieselguhr; photocatalysis

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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