Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第32卷    第9期    总第282期    2022年9月

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文章编号:1004-0609(2022)-09-2764-10
高杂质离子型稀土浸矿过程中硫酸铵用量参照依据
张朔1,秦磊1,王观石1,罗嗣海1, 2,彭陈亮1,邓国强3

(1. 江西理工大学 土木与测绘工程学院,赣州 341000;
2. 南昌航空大学 土木建筑学院,南昌 330000;
3. 龙岩稀土开发有限公司,龙岩 364000
)

摘 要: 采用数学统计方法分析了生产数据,研究不同参照依据和浸出率之间的关系:以福建某高杂质矿块为实验对象,进行不同浸矿剂用量工业实验;通过使用浸矿剂用量计算模型如化学平衡模型、修正DED模型和经验模型,评价不同参照依据和浸出率之间的相关性。结果发现:从经验模型看,阳离子交换总量单耗 (0.99)>矿土体积单耗 (0.96)>稀土质量单耗 (0.94);从理论模型看,修正DED模型中, (0.91)> (0.90)> (0.86)。由此可认为,阳离子交换总量和浸出率之间相关性最好。在此基础上,分析三个参照依据产生的浸矿剂用量误差原因,发现在高杂质环境下,以阳离子交换总量作为参照依据产生的相对误差最小。因此,综合相关性评价结果及理论分析,建议选择阳离子交换总量作为高杂质离子型稀土矿的浸矿剂用量参照依据。

 

关键字: 离子吸附型稀土;数学统计;浸矿剂用量计算模型;稀土含量;矿土体积;阳离子交换总量

Reference basis of ammonium sulfate dosage during leaching process of high impurity ionic rare earth
ZHANG Shuo1, QIN Lei1, WANG Guan-shi1, LUO Si-hai1, 2, PENG Chen-liang1, DENG Guo-qiang3

1. School of Civil and Surveying and Mapping Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China;
2. School of Civil Engineering and Architecture, Nanchang Hangkong University, Nanchang 330000, China;
3. Longyan Rare Earth Development Co., Ltd., Longyan 364000, China

Abstract:The amount of leaching agent for ionic rare earth ore is an important factor affecting the leaching rate, its reference basis determines the difference of estimated results. In the leaching process, the consumption of ammonium ions is related to the mass of rare earth, the volume of ore and the total amount of cation exchange, so these three factors can be used as a reference for the dosage of leaching agent. At present, the selection of reference basis in the industry relies more on traditional experience and lacks of evaluation of reference. In view of this problem, this paper adopts mathematical statistical method to the original leaching data, and studies the relationship between different reference basis and leaching rate: taking a ore block in Fujian Province, China as the experimental object, the experiment of injection with different dosages of leaching agent was carried out. Using the calculation model of leaching agent dosage, such as chemical equilibrium model, the modified DED model and experience model, the correlation between different reference basis and leaching rate were evaluated. The results show that, from the empirical model, (0.99)> (0.96)> (0.94), from the modified DED model, (0.919)> (0.90)> (0.86). Thus, it can be assumed that the correlation between the total cation exchange and leaching rate is the best. On this basis, the error causes of the amount of leaching agent produced by the three reference bases were analyzed. It is found that the relative error produced by the total cation exchange as reference basis is the smallest in the high impurity environment. Therefore, based on the correlation evaluation results and theoretical analysis, it is suggested to choose the total cation exchange as the reference basis for leaching agent dosage of high impurity ionic rare earth ore.

 

Key words: ion-absorbed rare earth; mathematical statistics; calculation model of leaching agent dosage; rare earth content; ore volume; cation exchange capacity

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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