(辽宁科技大学 矿业工程学院,鞍山 114001)
摘 要: 以含银方铅矿为研究对象,考查了丁铵黑药、乙基黄药、乙硫氮三种捕收剂,碳酸钠、石灰两种调整剂对其浮选行为的影响,并通过Zeta电位测定和吸附量测定进行捕收机理分析。浮选行为结果表明:含银方铅矿适合在弱碱性介质下回收,且含银量越高,上浮趋势越明显;与石灰相比,碳酸钠做调整剂时获得的含银方铅矿回收率更高;丁铵黑药是弱碱性介质下回收含银方铅矿较好的捕收剂,乙硫氮在强碱性介质中也可以回收含银方铅矿,但回收率偏低。机理分析结果表明:在弱碱性介质下,丁铵黑药不仅表面Zeta电位负移量明显高于其他两种药剂,而且在含银方铅矿表面的饱和吸附量也最大。根据热力学方法计算得到丁铵黑药和乙硫氮浮选含银方铅矿的临界pH值分别为9.27和10.81,与实际浮选规律一致。
关键字: 含银方铅矿;浮选;捕收机理;回收率
(School of Mining Engineering, University of Science and Technology Liaoning, Anshan 114051, China)
Abstract:Using the Ag-bearing galena as a research object, the influence of three types of ammonium dibutyl dithiophosphate (ADD), ethyl xanthate (EX), diethyldithiocarbamate (DDTC), sodium carbonate, lime two regulators on its flotation behavior were investigated. The capture mechanism analysis was carried out by Zeta potential measurement and adsorption measurement. The results of flotation behavior show that the Ag-bearing galena is suitable for recovery in weakly alkaline medium and the upward trend is more obvious with the increase of Ag content. Compared with lime, the recovery rate of Ag-bearing galena is higher when sodium carbonate is used as regulator. Ammonium dibutyl dithiophosphate (ADD) is a good collector for recovery of Ag-bearing galena in weakly alkaline medium, and diethyldithiocarbamate (DDTC) can also be recovered in strongly alkaline medium, but the recovery rate is low. The mechanism analysis results show that, in a weakly alkaline medium, not only the negative shift of Zeta potential on the surface of ammonium dibutyl dithiophosphate (ADD) is significantly higher than that of the other two medicaments, but also the saturated adsorption capacity on the surface of Ag-bearing galena is also the largest. According to the thermodynamic method, the critical pH values for the flotation of Ag-bearing galena in the flotation of ammonium dibutyl dithiophosphate (ADD) and diethyldithiocarbamate (DDTC) are 9.27 and 10.81, respectively, which are consistent with the actual flotation law.
Key words: Ag-bearing galena; flotation; collecting mechanism; recovery rate