Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 32    No. 7    July 2022

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Modeling and simulation of neodymium oxide dissolution in molten fluorides
Xin-yu WU1,2, Fei-fei LIU1, Jia-hao LI3, Xin-yu CHEN3, Shu-mei CHEN4

1. School of Electrical Engineering and Automation, Jiangxi University of Science and Technology, Ganzhou 341000, China;
2. Jiangxi Ionic Rare Earth Engineering Research Co., Ltd., Ganzhou 341000, China;
3. School of Mechanical and Electrical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China;
4. Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

Abstract:By combining the mass transfer mechanism of neodymium oxide with dissolution kinetics, a solution strategy for neodymium oxide dissolution was proposed to predict the dissolved neodymium oxide concentration during the process under complex flow field conditions. The factors affecting neodymium oxide dissolution were analyzed in detail. Aiming at the pulse feeding and continuous feeding modes in industrial practice, the characteristics of the dissolution process under the two feeding modes were compared. Simulation results showed that pulse feeding took shorter time to distribute evenly than continuous feeding. Finally, the dissolution time of single-particle neodymium oxide under static flow field conditions was compared with the literature results. Except for only one set of data with a maximum error of about 10%, the errors of other data are all within 5%.

 

Key words: neodymium oxide; dissolution; simulation; mass transfer; multiphase flow; molten salt; electrolysis

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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