(1. 矿冶科技集团有限公司冶金研究设计所,北京 100160;
2. 北京科技大学 冶金与生态工程学院,北京 100083)
摘 要: 深海多金属硫化物矿产资源富含铜、锌、钴、金、银等战略性金属,是人类未来开发利用的潜在资源之一。本文以多金属硫化物样品为研究对象,在工艺矿物学研究基础上,有针对性地开展了选冶联合工艺试验研究,分离提取了有用元素;确定了适合处理深海高硫细粒级铜锌多金属硫化物的“预浸-选矿富集-熔炼提取”选冶联合工艺,初步实现了样品中有价金属的回收,其中铜和锌的选冶综合回收率分别达到96.65%和90.31%,并结合深海多金属硫化物的特点,开发出了一种高效清洁的选冶药剂BK915,解决了高硫细粒级铜锌多金属硫化物分选难题,为深海多金属硫化物开发提供技术参考。
关键字: 深海;多金属硫化物;工艺矿物学;浮选;冶金
(1. BGRIMM Technology Group, Beijing 100160, China;
2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China)
Abstract:Deep-sea polymetallic sulfide mineral resources are rich in copper, zinc, cobalt, gold, silver and other strategic metals, which is one of the potential resources for future development and utilization of human beings. In this paper, mineral processing and metallurgical processes of a deep sea polymetallic sulphide were studied, and useful elements were separated and extracted. The “pre-leach-beneficiation-smelting extraction” suitable for high sulfur fine-grain copper-zinc polymetallic sulfide was determined, and the preliminary recovery of valuable metals in the samples was realized, and the comprehensive recovery rate of copper and zinc reached 96.65% and 90.31%, respectively. Combining the characteristics of the deep-sea polymetallic sulfide, an efficient and clean agent BK915 was developed, which solved the problem of separation of high sulfur fine-grained copper-zinc polymetallic sulfides and provided a technical reference for the subsequent development of deep sea polymetallic sulfides.
Key words: deep sea; polymetallic sulfide; process mineralogy; floatation; metallurgy