(1. 河南科技大学 材料科学与工程学院,洛阳 471023;
2. 有色金属新材料与先进加工技术省部共建协同创新中心,洛阳 471023;
3. 有研工程技术研究院有限公司,北京 100088;
4. 中南大学 材料科学与工程学院,长沙 410083;
5. 河南理工大学 机械与动力工程学院,焦作 454000;
6. 兰州理工大学 材料科学与工程学院,兰州 730050;
7. 重庆材料研究院有限公司,重庆 400700;
8. 河南森格材料科技有限公司,焦作 454010;
9. 常州恒丰特导股份有限公司,常州 213000;
10. 河南优克电子材料有限公司,济源 454650;
11. 浙江东尼电子股份有限公司,湖州 313008)
摘 要: 铜基丝线材广泛应用于集成电路键合线、音视频传输线缆、医疗器械有源线束以及各种电子元器件,是保障系统电流和信号稳定传输的关键导体材料。本文围绕铜基丝线材制备工艺流程,综述热型水平连铸、冷型竖引连铸制备铜基杆坯的工艺特点及其与定向凝固组织之间的关系,阐述超细超精连续拉拔、热处理、表面涂镀等工艺参数对晶粒、析出相、表面镀层以及键合特征的影响规律,最后叙述了“新基建”背景下铜基丝线材应用领域和装备技术方面的发展趋势。
关键字: 铜基材料;丝线材;热型水平连铸;冷型竖引连铸;连续拉拔;表面涂镀
(1.School of Material Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China;
2. Provincial and Ministerial Co-construction Collaborative Innovation Center of Nonferrous New Materials and Advanced Processing Technology, Luoyang 471023, China;
3. General Research Institute for Nonferrous Metals, Beijing 100088, China;
4. School of Materials Science and Engineering, Central South University, Changsha 410083, China;
5. School of Mechanical Engineering, Henan Polytechnic University, Jiaozuo 454000, China;
6. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;
7. Chongqing Materials Research Institute Co., Ltd., Chongqing 400700, China;
8. Henan Senger Materials Technology Co., Ltd., Jiaozuo 454010, China;
9. Changzhou Hengfeng Special Conductor Co., Ltd., Changzhou 213000, China;
10. Henan Youke Electronic Materials Co., Ltd., Jiyuan 454650, China;
11. Zhejiang Tony Electronic Co., Ltd., Huzhou 313008, China)
Abstract:The copper wires are widely used in integrated circuit bonding wire, audio and video transmission cable, active wiring harness of medical devices, and various electronic components. It is the key conductor material to ensure the stable transmission of system current and signal. Based on the preparation process of copper wire, this paper reviews the process characteristics of hot mold horizontal continuous casting and cold mold vertical continuous casting, and their relationship with the directional solidification structure of as-cast copper rod. The effects of process parameters such as continuous drawing, heat treatment, and surface coating on the characteristics of grain size, precipitated phase, surface coating, and bonding were discussed. Finally, the development trend of application field and equipment technology of copper based wire under the background of “new infrastructure construction” was prospected.
Key words: copper based materials; wire; hot mould horizontal continuous casting; cold mould vertical continuous casting; continuous drawing; surface coating