Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 29    No. 10    October 2019

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Precipitate evolution in Mg-7Gd-3Y-1Nd-1Zn-0.5Zr alloy during isothermal ageing at 240 °C
Wei LIU1,2, Zhi-wei DU1, 2, 3, Ting LI1, 2, 3, Kui ZHANG4, Xiao-lei HAN1,2, Yong-gang PENG1,2, Jing ZHANG1,2, Jia-wei YUAN4, Shu-feng LIU1,2, Zheng PANG1,2

1. Guobiao (Beijing) Testing & Certification Co., Ltd., Beijing 100088, China;
2. National Center of Analysis and Testing for Nonferrous Metals and Electronic Materials, GRINM Group Co., Ltd., Beijing 100088, China;
3. China United Test & Certification Co., Ltd., Beijing 100088, China;
4. State Key Laboratory of Non-ferrous Metals & Processes, GRIMAT Engineering Institute Co., Ltd., Beijing 101407, China

Abstract:The morphology and crystal structure of the precipitates in Mg-7Gd-3Y-1Nd-1Zn-0.5Zr alloy during isothermal ageing at 240 °C were investigated using transmission electron microscopy (TEM) and high-angle annular dark-?eld scanning transmission electron microscopy (HAADF-STEM). After under-ageing for 2 h, the precipitates in the alloy are ordered solute clusters with rare earth atomic columns exhibiting hexagonal ring structure, zigzag GP zones and β'''' in its early formation. After peak-ageing for 18 h, the precipitates are mainly β'''' and new rod-like β''''p accompanied with β''''. After over-ageing for 100 h, the precipitates are β'''', β1, long-period stacking ordered (LPSO) building block known as γ′ and 14H-LPSO. β'''' has the three-dimensional shape of convex lens with smaller length-to-width ratio viewed along á0001?α than that in the EW75 alloy. The excellent thermal stability of this alloy can be attributed to the γ'''' and 14H-LPSO retarding the growth of β'''' and β1, low diffusion rate of rare earth atoms and physical character of β'''' and β1.

 

Key words: magnesium alloy; ageing; precipitate; long-period stacking ordered (LPSO) phase

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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