Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 29    No. 9    September 2019

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Adsorption mechanism of sodium oleate and styryl phosphonic acid on rutile and amphibole surfaces
Wei XIAO1,2, Ya-xin REN1, Juan YANG1, Pan CAO2, Jun WANG2, Wen-qing QIN2, Guan-zhou QIU2

1. School of Resources Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China;
2. School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China

Abstract:A reagent combination of sodium oleate (NaOl) and salicyl hydroximic acid was employed as the roughing and scavenging collectors, whereas styryl phosphoric acid (SPA) and octanol were employed as the cleaning collectors. Results of bench-scale flotation demonstrate that the dosage of SPA can be reduced by about 80%, and that a better flotation index can be obtained using the proposed reagent system. The results of adsorption amount and contact angle measurements indicate that the rutile surface adsorbed not only a large amount of residual NaOl but also SPA and a small amount of NaOl remained on the amphibole surface in strong acidic solution. The hydrophobic difference between rutile and amphibole surfaces was therefore amplified in cleaning, and their further separation became much easier consequently.

 

Key words: rutile; amphibole; flotation separation; combined collector; synergistic adsorption mechanism

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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