Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

您目前所在的位置:首页 - 期刊简介 - 详细页面

中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 28    No. 9    September 2018

[PDF Download]        

    

Hydrogen storage performances of as-milled REMg11Ni (RE=Y, Sm) alloys catalyzed by MoS2
Yang-huan ZHANG1,2, Wei ZHANG1,2, Ze-ming YUAN1,2, Wen-gang BU2, Yan QI2, Xiao-ping DONG3, Shi-hai GUO2

1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China;
2. Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, China;
3. Department of Mechanical Engineering, Hebei University, Baoding 071002, China

Abstract:To compare the hydrogen storage performances of as-milled REMg11Ni-5MoS2 (mass fraction) (RE=Y, Sm) alloys, which were catalyzed by MoS2, the corresponding alloys were prepared. The hydrogen storage performaces of these alloys were measured by various methods, such as XRD, TEM, automatic Sievert apparatus, TG and DSC. The results reveal that both of the as-milled alloys exhibit a nanocrystalline and amorphous structure. The RE=Y alloy shows a larger hydrogen absorption capacity, faster hydriding rate, lower initial hydrogen desorption temperature, superior hydrogen desorption property, and lower hydrogen desorption activation energy, which is thought to be the reason of its better hydrogen storage kinetics, as compared with RE=Sm alloy.

 

Key words: Mg-based alloy; ball milling; catalyst; rare earth element; hydrogen storage performance

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中国科学技术协会 主办:中国有色金属学会 承办:中南大学
湘ICP备09001153号 版权所有:《中国有色金属学报》编辑部
------------------------------------------------------------------------------------------
地 址:湖南省长沙市岳麓山中南大学内 邮编:410083
电 话:0731-88876765,88877197,88830410   传真:0731-88877197   电子邮箱:f_ysxb@163.com