Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 27    No. 9    September 2017

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Nucleation interface of Al-Sb alloys on single crystal Al2O3 substrate
Lu WANG1,2, Lin YANG2, Di ZHANG1, Ming-xu XIA1, Yun WANG3, Bin CHEN1, Jian-guo LI1

1. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China; 2. School of Materials and Engineering, Jiangsu University of Technology, Changzhou 213001, China; 3. BCAST, Brunel University, Uxbridge, Middlesex UB8 3PH, UK

Abstract:Lattice structure information of heterogeneous nucleation at nucleation interface was present. The crystal orientation, and interfacial structure characteristic of liquid Al alloys nucleated on the basal surface (0001) Al2O3 single crystal substrate were identified by X-ray diffraction (XRD), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM) analysis. The preferred crystal orientations of pure Al and Al-1%Sb (mass fraction) alloy adjacent to the nucleation interface were examined as (200) and (220) planes of Al, respectively, and two corresponding orientation relationships were obtained. An improved nucleation efficiency and refined grains were attributed to both the reduced interplanar spacing of preferred orientation and the decrease of lattice misfit from 16.4% to 7.0% in Al-1%Sb/Al2O3 nucleation group.

 

Key words: aluminium alloy; nucleation; interfacial structure; orientation relationship

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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