中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 26 No. 9 September 2016 |
(1. College of Chemistry and Chemical Engineering,
Hunan Institute of Science and Technology, Yueyang 414006, China;
2. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
3. College of Chemical Engineering, Xiangtan University, Xiangtan 411105, China)
Abstract:ZnO/NiO/ZnAl2O4 mixed-metal oxides were successfully synthesized through a hydrotalcite-like precursor route, in which appropriate amounts of metal salts solutions were mixed to obtain a new series of ZnNiAl layered double hydroxides (LDHs) as precursors, followed by calcination under different temperatures. The as-obtained samples were characterized by SEM, HRTEM, TEM, XRD, BET, TG-DTA, and UV-Vis spectra techniques. The photocatalytic activities of the samples were evaluated by degradation of methyl orange (MO) under the simulated sunlight irradiation. The effects of Zn/Ni/Al mole ratio and calcination temperature on the composition, morphology and photocatalytic activity of the samples were investigated in detail. The results indicated that compared with ZnNiAl-LDHs, the mixed-metal oxide showed superior photocatalytic performance for the degradation of MO. A maximum of 97.3% photocatalytic decoloration rate within 60 min was achieved from the LDH with the Zn/Ni/Al mole ratio of 2:1:1 and the calcination temperature of 500 °C, which much exceeded that of Degussa P25 under the same conditions. The possible mechanism of photocatalytic degradation over ZnO/NiO/ZnAl2O4 was discussed.
Key words: ZnNiAl layered double hydroxide; mixed oxide; photocatalytic degradation; phototatalytic activity