Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 26    No. 8    August 2016

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Electrochemical hydriding and thermal dehydriding properties of nanostructured hydrogen storage MgNi26 alloy
V. KNOTEK1, O. EKRT1, M. LHOTKA2, D. VOJTěCH1

1. Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague,
Technická 5, 166 28 Prague 6, Czech Republic;
2. Department of Inorganic Technology, University of Chemistry and Technology Prague,
Technická 5, 166 28 Prague 6, Czech Republic

Abstract:The MgNi26 alloy was prepared by three different methods of gravity casting (GC), mechanical alloying (MA) and rapid solidification (RS). All samples were electrochemically hydrided in a 6 mol/L KOH solution at 80 °C for 240 min. The structures and phase compositions of the alloys were studied using optical microscopy and scanning electron microscopy, energy dispersive spectrometry and X-ray diffraction. A temperature-programmed desorption technique was used to measure the absorbed hydrogen and study the dehydriding process. The content of hydrogen absorbed by the MgNi26-MA (approximately 1.3%, mass fraction) was 30 times higher than that of the MgNi26-GC. The MgNi26-RS sample absorbed only 0.1% of hydrogen. The lowest temperature for hydrogen evolution was exhibited by the MgNi26-MA. Compared with pure commercial MgH2, the decomposition temperature was reduced by more than 200 °C. The favourable phase and structural composition of the MgNi26-MA sample were the reasons for the best hydriding and dehydriding properties.

 

Key words: magnesium alloy; hydrogen storage; electrochemical hydriding; mechanical alloying; melt spinning

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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