Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 26    No. 5    May 2016

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Preparation and oxygen permeability of Bi26Mo10O69 porous layer modified ionic-electronic mixed conductor on air side
Tai-he WANG1, Rong LI1, Qiang ZHEN1,2, Lin CHENG1

1. Nano-Science and Technology Research Center, Shanghai University, Shanghai 200444, China;
2. School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China

Abstract:Bi26Mo10O69 nanopowder was prepared by hydrothermal method and used as a surface modification material for oxygen separation membrane to enhance oxygen permeability. Thermal decomposition behavior and phase variation of the precursor were investigated by thermal analyzer (TG-DSC) and high-temperature X-ray diffraction (HT-XRD). Bi26Mo10O69 porous layer was coated on the air side of BaCo0.7Fe0.2Nb0.1O3-d (BCFN) oxygen permeable membrane by dipping method. In the partial oxidation experiment of coke oven gas (COG), the Bi26Mo10O69-coated BCFN membrane exhibits higher oxygen permeability and CH4 conversion than the uncoated BCFN membrane. When the thickness of BCFN membrane was 1 mm and the COG and air fluxes were 120 and 100 mL/min, the oxygen permeation flux reached 16.48 mL/(min·cm2) at 875 °C, which was 16.96% higher than the uncoated BCFN membrane. Therefore, Bi26Mo10O69 porous layer on the air side will be promising modification coating on the oxygen permeability of BCFN membrane.

 

Key words: Bi26Mo10O69; porous-coating; BaCo0.7Fe0.2Nb0.1O3-d (BCFN); oxygen permeation flux

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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