Abstract:A new Ni-based superalloy Ni48Cr28W5Co3Mn1Si1.6 was developed and the influence of a trace amount of rare earth (RE) metal addition on the oxidation resistance of this alloy was investigated. Isothermal oxidation behavior was investigated at 950-1150 °C in air, and then analyzed using scanning electronic microscopy and X-ray diffraction. The results showed that oxidation mass gain kinetics of the samples with and without RE elements follow the parabolic law. The effect of 0.20% RE on oxidation resistance is relatively small, and the oxidation rate constant of the alloy modified with 0.20% RE addition decreases by 5.9%-9.0%. Oxidation at 950-1150 °C for 100 h results in the formation of MnCr₂O₄, Cr₂O₃ and SiO₂. A continuous and protective MnCr₂O₄ spinel layer forms as outer layer. The continuous middle oxide layer is confirmed to be Cr₂O₃, and the innermost layer consists of discontinuous SiO₂.

Key words: Ni-based superalloy; rare earth element; high temperature oxidation; multi-layered oxides