Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 26    No. 3    March 2016

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Synthesis of niobium borides by powder metallurgy methods usingNb2O5, B2O3 and Mg blends
?zge Balc?, Duygu A?ao?ullar?, M. Lütfi ?ve?o?lu, ?smail Duman

Faculty of Chemical and Metallurgical Engineering, Department of Metallurgical and Materials Engineering, Particulate Materials Laboratories, ?stanbul Technical University, Ayaza?a Campus, 34469 Maslak, ?stanbul, Turkey

Abstract:Niobium boride powders having NbB, NbB2 and Nb3B4 phases in various amounts and single phase NbB powders were successfully synthesized by using powder metallurgy methods from related metal oxide raw materials in the presence of a strong reducing agent. Nb2O5, B2O3 and Mg powder blends were milled at room temperature by a high-energy ball mill for different time. Subsequently, undesired MgO phase was removed from the milled powders by HCl leaching to constitute NbB-NbB2-Nb3B4 as final products and they were subjected to an annealing process at 1500 °C for 4 h to observe probable boride transformation. Characterization was carried out by XRD, DSC, PSA, SEM/EDX, TEM and VSM. The effects of milling time (up to 9 h) on the formation, microstructure and thermal behavior of the final products were investigated. Reduction reaction took place after milling stoichiometric powder blends for 2 h. Nano-sized NbB-NbB2-Nb3B4 powders in high purity were obtained in the absence of any secondary phase and any impurity via mechanochemistry by milling for 5 h and leaching with 4 mol/L HCl. After annealing, pure and nano-sized NbB-NbB2-Nb3B4 powders transformed to a single NbB phase without leaving behind NbB2 and Nb3B4 phases.

 

Key words: niobium boride powders; powder metallurgy; mechanochemical synthesis; annealing; microstructure

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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