Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

您目前所在的位置:首页 - 期刊简介 - 详细页面

中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第26卷    第3期    总第204期    2016年3月

[PDF全文下载]        

    

文章编号:1004-0609(2016)-03-0630-06
撞击流反应器制备纳米铜粉过程的流场多尺度分析
罗燕1, 2,周剑秋1, 2,郭钊2,周玉新3,郭嘉3,杨侠2

(1. 南京工业大学机械与动力工程学院,南京 210009;
2. 武汉工程大学机电工程学院,武汉 430073;
3. 武汉工程大学化工与制药学院,武汉 430073
)

摘 要: 在撞击流技术制备纳米铜粉的实验反应体系中,粒径的分布规律与流场混合尺度存在某种联系。采用数值计算方法,从流场多尺度角度开展液体连续相撞击流反应器(LISR)强化制备过程分析。结果表明:大尺度流体对流由桨叶旋转带动,中等尺度湍流扩散强度与湍黏度和速度梯度关联,小尺度流体黏性扩散与中等尺度湍流扩散类似;LISR为制备纳米铜粉反应体系提供一个强烈压力波动区,其微观状态下的反应体系随着压力波动区能量的传递和转换得以迅速实现,并显著促进制备纳米铜粉反应过程的进行;LISR中湍黏扩散作用显著,能高效促进流体更加均匀,有利于制备纳米铜粉反应体系。上述过程流场的多尺度分析,对后期撞击流技术制备纳米铜粉的实验反应体系工艺优化具有指导意义。

 

关键字: 撞击流反应器;纳米铜粉;流场;多尺度分析;数值模拟

Flow field multi-scale analysis of impinging stream reactor forpreparing nano copper powder process
LUO Yan1, 2, ZHOU Jian-qiu1, 2, GUO Zhao2, ZHOU Yu-xin3, GUO Jia3, YANG Xia2

1. School of Mechanical and Power Engineering, Nanjing Technology University, Nanjing 210009, China;
2. School of Mechanical and Electrical Engineering, Wuhan Institute of Technology, Wuhan 430073, China;
3.School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430073, China

Abstract:In the experiment system of preparing nano-copper powder in impinging stream reactor, there is an association between particle size distribution and flow mixing scale. The strengthened preparation process in liquid-continuous impinging streams reactor (LIRS) was analyzed by numerical computation from multi-scale standpoint. The results show that the large-scale convection is driven by rotating blades, the medium-scale turbulence diffusion intensity and turbulent viscosity are associated with velocity gradient,and small-scale viscosity diffusion is similar with that of medium-scale turbulent diffusion. LISR provides the reaction system with a strong pressure fluctuation zone, in which the micro reaction system can quickly be realized and promoted with the energy transfer and conversion. The remarkable turbulent viscous diffusion can effectively accelerate the fluid more uniform and be conducive to the reaction system. The multi-scale analysis of the flow field above has guiding significance for the optimization of the latter preparing of the impinging stream technology of nano-copper powder reaction system.

 

Key words: impinging stream reactor; nanometer copper powder; flow field; multi scale analysis ;numerical simulation

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中国科学技术协会 主办:中国有色金属学会 承办:中南大学
湘ICP备09001153号 版权所有:《中国有色金属学报》编辑部
------------------------------------------------------------------------------------------
地 址:湖南省长沙市岳麓山中南大学内 邮编:410083
电 话:0731-88876765,88877197,88830410   传真:0731-88877197   电子邮箱:f_ysxb@163.com