Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第25卷    第12期    总第201期    2015年12月

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文章编号:1004-0609(2015)12-3439-06
超重力场反应熔铸合成TiB2基复相陶瓷刀具材料
潘传增,张靖,张龙

(军械工程学院先进材料研究所,石家庄050003)

摘 要: 通过超重力场反应熔铸合成TiB2基复相陶瓷刀具材料,研究材料的物相组成、组织结构及力学性能,探讨材料中典型组织的形成过程。结果表明:反应产物由TiB2与TiC两相构成,尺寸约为2 μm的TiB2柱状晶构成陶瓷基体,TiC晶粒不规则地分布于TiB2晶粒之间,二者结合紧密,呈现出典型的凝固组织特征。所得反应产物的相对密度为93.2%,维氏显微硬度值为21.4 GPa,抗弯强度为258 MPa,断裂韧性为4.6 MPa?m0.5。分析认为超重力场促进Ti-B-C中间熔体的生成,是合成TiB2基复相陶瓷的关键。

 

关键字: TiB2;超重力场;反应熔铸;刀具

Reactive casting of multiphase TiB2-based ceramics for cutting materials in high-gravity field
PAN Chuan-zeng, ZHANG Jing, ZHANG Long

Institute of Advanced Materials, Ordnance Engineering College, Shijiazhuang 050003, China

Abstract:Thereactive casting processing was used to synthesize the TiB2-based multiphase ceramics for cutting materials in high-gravity field. The phase composition, microstructures, mechanical properties and forming mechanism of the products were studied. The results show that the products contain TiB2 and TiC phases; the matrix consists of TiB2 columnar crystals in size range of 2 μm which approximately distribute between the irregular TiC crystals regularly. The ceramics are presented with typical solidified morphologies, the TiB2 crystals are well-bonded with TiC. The relative density, Vickers micro-hardness, bending strength and fracture toughness of products are 93.2%, 21.4 GPa, 258 MPa and 4.6 MPa?m0.5, respectively. It is proposed that the formation of Ti-B-C intermediate melt promoted by high gravity field is the key factor for fabricating multiphase TiB2-based ceramics.

 

Key words: TiB2; high gravity field; reactive casting; cutting material

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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