Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 25    No. 12    December 2015

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Magnetic and optical properties ofzinc chromite nanostructures prepared by microwave method
Zahra MOUSAVI, Mahdiyeh ESMAEILI-ZARE, Masoud SALAVATI-NIASARI

Institute of Nano Science and Nano Technology, University of Kashan, Kashan 87317-51167, Iran

Abstract:The nanostructures of zinc chromite (ZnCr2O4) were fabricated by the microwave method. It was shown that the well-crystallized spinel structure is formed after annealing at 700 °C. The influence of reaction time and irradiation power of oven on the size and shape of the as-prepared ZnCr2O4 samples was studied. The synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy, Fourier transform infrared (FTIR) spectra and vibrating sample magnetometry (VSM), respectively. The optical band gap calculated using DRS was found to be 3.50 eV for ZnCr2O4 nanostructures. Photoluminescence measurements also confirmed this result.

 

Key words: zinc chromite; nanostructures; superhydrophilicty; magnetic property; optical property

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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