Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 25    No. 10    October 2015

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Corrosion of in-situ grown MgAl-LDH coating on aluminum alloy
Fen ZHANG1, Chang-lei ZHANG1, Liang SONG2, Rong-chang ZENG1, Zhen-guo LIU1,Hong-zhi CUI1

1. College of Materials Science and Engineering,
Shandong University of Science and Technology, Qingdao 266590, China;
2. Qingdao Institute of Bioenergy and Bioprocess Technology,Chinese Academy of Sciences, Qingdao 266101, China

Abstract:MgAl-layered double hydroxides (LDH) coatings were fabricated by the in-situ hydrothermal treatment method on the AA5005 aluminum alloy. The characteristics of the coatings were investigated by XRD, FT-IR, SEM and EDS.The effect of the pH value of the solution on the formation of the LDH coatings was studied. The optimum pH value of the solution was 10.0. The corrosion resistance of the LDH coatings was studied using potentiodynamic polarization tests and electrochemical impedance spectrum (EIS). The results demonstrate that the LDH coatings, characterized by platelets vertically to the substrate surface possess excellent corrosion resistance. The influence of the hydrothermal crystallization time on the corrosion resistance was evaluated. Prolonging the crystallization time can increase the corrosion resistance of the obtained LDH coatings. The anticorrosion mechanism of the LDH coatings was discussed.

 

Key words: aluminum alloy; layered double hydroxide; coating; corrosion

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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