Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 25    No. 6    June 2015

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Kinetic studies of gold recovery from dilute aqueous solutions using Fe2+ chloride ions
Marek WOJNICKI, Krzysztof FITZNER, Magdalena LUTY-B?OCHO

Faculty of Non-Ferrous Metals, AGH University of Science and Technology, Krakow 30-059, Poland

Abstract:The kinetics of Au3+ chloride complex ions reduction using Fe2+ chloride ions was investigated by stopped-flow method. The influence of initial concentrations of Au3+ chloride ions, Fe2+ ions, chloride ions, neutral salt (NaClO4), pH of the solution and temperature was investigated. Activation energy was determined to be 42.36 kJ/mol. Moreover, the kinetic equation was postulated. Obtained solid phase was analyzed using SEM techniques. Particles size varies in the range from 0.5 to 5 μm. It was shown that gold can be removed from the solution by the reduction of Au3+ chloride ions and filtration of precipitant.

 

Key words: gold recovery; reduction; recycling; electronic waste

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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