中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 24 No. 12 December 2014 |
（1. National Engineering Research Center of Light Alloy Net Forming,
Shanghai Jiao Tong University, Shanghai 200240, China;
2. State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China）
Abstract:Electroless nickel plating on AZ91D substrate with a new and eco-friendly pretreatment process based on tuning an electrochemical homogeneous surface was investigated. The morphology, deposition process, chemical composition and microstructure of Ni-P coating were studied. It is indicated that β phases are selectively removed, producing a microstructural homogeneous surface and the subsequent uniform and compact Zn immersion layer. A defect-free and well adhesive Ni-P coating can be successfully obtained due to its uniform nucleation and growth based on such pretreatment. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests reveal that Ni-P coating could significantly improve the corrosion resistance of AZ91D substrate.
Key words: AZ91D magnesium alloy; homogenization pretreatment; electroless nickel plating; corrosion
