Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第24卷    第11期    总第188期    2014年11月

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文章编号:1004-0609(2014)11-2805-08
铝合金表面激光熔覆NiCrAl/TiC复合涂层的磨损行为和耐蚀性能
李 琦,刘洪喜,张晓伟,姚 爽,张 旭

(昆明理工大学 材料科学与工程学院,昆明 650093)

摘 要: 为提高铝合金的摩擦磨损和耐蚀性能,在A390铝合金基体上通过激光熔覆制备NiCrAl/TiC复合涂层。采用XRD和EDS分析了涂层的物相组成,结合SEM观察了涂层的微观组织,运用摩擦磨损试验机和电化学工作站测试了涂层的摩擦磨损和耐腐蚀性能。结果表明:复合涂层主要物相为AlNi、Al3Ni2、TiC,同时含有少量的Cr13Ni5Si2、Cu9Al4和α(Al)。涂层自下至上分别为短棒状树枝晶、胞状晶、柱状树枝晶和等轴晶。相同磨损条件下,A390基体发生了严重的磨粒磨损和剥层磨损,而激光熔覆涂层只产生了轻微的磨粒磨损,熔覆层的相对耐磨性为3.16。在3.5% NaCl溶液中的极化曲线和电化学阻抗谱(EIS)显示:熔覆层自腐蚀电位较A390基体的正移,腐蚀电流密度减小;熔覆层呈单容抗特性,而A390基体在高频区表现为容抗特性,在中低频区则为感抗特性。在Bote图中,低频区熔覆层对应的相位角和中低频段熔覆层的阻抗模值均大于A390基体的,表明熔覆层的耐蚀性远高于A390基体的。熔覆层的腐蚀形貌为局部点蚀,A390基体的腐蚀形貌为晶间腐蚀和剥蚀。

 

关键字: 铝合金;复合涂层;激光熔覆;磨损行为;耐蚀性能

Wear behavior and corrosion resistance of NiCrAl/TiC composite coating on aluminum alloy by laser cladding
LI Qi, LIU Hong-xi, ZHANG Xiao-wei, YAO Shuang, ZHANG Xu

Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Abstract:In order to improve the frictional wear behavior and corrosion resistance of aluminum alloy, NiCrAl/TiC composite coating was fabricated on A390 aluminum alloy by laser cladding. The phase constitution, microstructure, frictional wear behavior and corrosion resistance of the composite coating were analyzed using X-ray diffraction (XRD), energy dispersive spectrum (EDS), scanning electron microscope (SEM), friction and wear testing machine and electrochemical workstation. The results show that the coating is mainly composed of AlNi, Al3Ni2 and TiC phases, and a small amount of Cr13Ni5Si2, Cu9Al4 and α(Al) phases. The microstructures of the coating from the bottom to top are dendrite crystal, cellular crystal, columnar dendrite crystal and equiaxed crystal, respectively. Under the same wear condition, A390 substrate exhibits serious abrasive wear and peeling characteristics, while the cladding coating exhibits slight abrasive wear behavior. The relative wear resistance of cladding coating is 3.16. The polarization curves and electrochemical impedance spectroscopy (EIS) in 3.5% NaCl solution indicate that the corrosion potential of the coating is more positive than that of the matrix, and the corrosion current density decreases significantly. The coating exhibits capacitive reactance behavior, but A390 substrate exhibits capacitive reactance in high frequency area and impedance in medium low frequency area. In Bote diagram, the phase angle of composite coating in low frequency area and the impedance modulus value of coating in low-middle frequency are larger than those in the matrix. This proves that the composite coating has better corrosion resistance compared to that of A390 aluminum alloy. The corrosion morphology of the cladding coating is localized pitting, but the corrosion morphology of A390 matrix is intergranular corrosion and erosion.

 

Key words: aluminum alloy; composite coating; laser cladding; wear behavior; corrosion resistance

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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