Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 24    No. 10    October 2014

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Kinetics and mechanism of adsorptive removal of copper from aqueous solution with poly(vinyl alcohol) hydrogel
Tongsai JAMNONGKAN1, Krittiya KANTAROT1, Kitiya NIEMTANG1, P. Pungboon PANSILA1, Amnuay WATTANAKORNSIRI2

1. Department of Fundamental Science and Physical Education, Faculty of Science at Siracha,
Kasetsart University, Chonburi 20230, Thailand;
2. Department of Agriculture and Environment, Faculty of Science and Technology,
Surindra Rajabhat University, Surin 32000, Thailand

Abstract:Recently, a renewed interest in techniques for heavy metal removal of wastewater has been growing because of embarking opportunities for industrial applications. We investigated the adsorption capacity of the copper on the poly (vinyl alcohol) hydrogel from the aqueous solution. Chemical structure and water absorption of the hydrogel were studied using FTIR and water uptake measurement, respectively. The results showed that the poly (vinyl alcohol) was crosslinked with glutaraldehyde, and the hydrogel highly exhibited the equilibrium swelling ratio because of its hydrophilicity property. Additionally, it was found that the adsorption process followed the pseudo-second-order kinetics and the mechanism diffusion was controlled by particle and film diffusions.

 

Key words: heavy metals removal; hydrogel; wastewater; adsorption; diffusion mechanism

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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