中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 24 No. 9 September 2014 |
(Department of Metallurgical and Material Engineering, Jadavpur University, Kolkata-700032, India)
Abstract:Titaniferous magnetite ore is a kind of symbiotic complex ore which comprises ilmenite, magnetite, hercynite and magnesio-hercynite spinel minerals. The ore collected from eastern India was characterized by XRD, WDXRF, SEM and M?ssbauer spectroscopy. The oxidation behaviour of fine ore was investigated by TG-DTA analysis under oxygen atmosphere. Subsequent isothermal oxidation experiments were carried out under oxygen and air atmospheres, holding the samples for different periods of time at different temperatures from 873 K to 1473 K. It was observed that ilmenite phase transformed to hematite and titanium dioxide at lower temperature, whereas ferric-pseudobrookite phase was found at higher temperature. Direct reduction of oxidized sample-coke cylindrical briquettes was successfully achieved for phase transition from titaniferous magnetite to iron and titanium dioxide at 1473 K.
Key words: titaniferous magnetite; thermal analysis; phase analysis; oxidation; reduction