Abstract:The microstructural evolution during directional solidification of the Ni-25%Al (mole fraction) alloy was investigated in the range of growth velocity from 10 to 100 μm/s under a given thermal gradient of 10 K/mm. The solidification microstructures reveal a transition from γ''''-β equilibrium eutectic to γ-β metastable eutectic plus β dendrites. A mixed microstructure of γ''''-β and γ-β eutectics produced at a growth velocity of 25 μm/s illustrates that the transition occurs during the competitive growth between γ and γ'''' phases. The growth temperature for each phase was considered to understand the microstructure selection during solidification. The experimental results show that a phase or a microstructure solidifying with the highest temperature under a given growth condition is preferentially selected upon solidification. In addition, both stable eutectic and metastable eutectic are shown to coexist and simultaneously grow in the velocity range between 25 and 60 μm/s due to their similar growth temperatures.

Key words: Ni-Al alloys; directional solidification; intermetallic compound; undercooling; eutectic; growth velocity; microstructure