Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 23    No. 12    December 2013

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Synthesis of Cu2O/reduced graphene oxide composites as anode materials for lithium ion batteries
Guo-chun YAN, Xin-hai LI, Zhi-xing WANG, Hua-jun GUO,Qian ZHANG, Wen-jie PENG

School of Metallurgy and Environment, Central South University, Changsha 410083, China

Abstract:A facile way was used to synthesize Cu2O/reduced graphene oxide (rGO) composites with octahedron-like morphology in aqueous solution without any surfactant. TEM images of the obtained Cu2O/rGOs reveal that the Cu2O particles and rGO distribute hierarchically and the primary Cu2O particles are encapsulated well in the graphene nanosheets. The electrochemical performance of Cu2O/rGOs is enhanced compared with bare Cu2O when they are employed as anode materials for lithium ion batteries. The Cu2O/rGO composites maintain a reversible capacity of 348.4 mA×h/g after 50 cycles at a current density of 100 mA/g. In addition, the composites retain 305.8 mA×h/g after 60 cycles at various current densities of 50, 100, 200, 400 and 800 mA/g.

 

Key words: cuprous oxide; reduced graphene oxide; anode material

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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