中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 23 No. 11 November 2013 |
(Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,
School of Chemistry and Biological Engineering, Changsha University of Science and Technology,
Changsha 410004, China)
Abstract:A thin layer of TiO2 film was deposited on ITO surface via the liquid phase deposition (LPD) process. The photocurrent and electrochemical impedance spectroscopy (EIS) measurements indicated that the as-prepared LPD TiO2/ITO film had an excellent photoelectrochemical performance, which showed a sensitive and rapid response to the UV irradiation. The photogenerated electron-hole pairs could be effectively separated by applying an external bias to the TiO2 film electrode. The LPD TiO2/ITO film was employed to study the photoelectrocatalytic (PEC) degradation of 4-aminoantipyrine. Compared with other techniques, the PEC technique based on such a LPD film electrode had a synergetic effect for 4-aminoantipyrine degradation. When the applied bias potential was +0.8 V and the supporting electrolyte concentration of Na2SO4 was 0.1 mol/L, the highest degradation efficiency within 120 min could reach 95% for 0.1 mmol/L 4-aminoantipyrine solution at pH 2.0.
Key words: liquid phase deposition; TiO2 film electrode; photoelectrocatalysis; 4-aminoantipyrine