Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第22卷    第9期    总第162期    2012年9月

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文章编号:1004-0609(2012)09-2572-06
泡沫铝表面镀镍及其性能
刘  欢1,姚广春1,曹卓坤1,华中胜2,史建超1

(1. 东北大学 材料与冶金学院,沈阳 110004;
2. 安徽工业大学 冶金与资源学院,马鞍山 243002
)

摘 要: 为提高泡沫铝耐高温及耐蚀性,对其表面电镀镍层。采用扫描电镜观察镀层的表面形貌,进行镀层与基体的结合力测试、常温及650 ℃以上高温压缩测试及常温下中性电化学腐蚀研究。结果表明:一定范围内,电流密度越大,镀层结晶越致密;但电流密度过大(≥3 A/dm2)时,镀层区域结晶反而粗大;由于走位剂的添加,深镀能力提高;镀层与基体结合良好,在电流密度为1 A/dm2、镀层厚度为28~30 µm时,镍层与基体界面结合力达到最大;镀镍后的泡沫铝压缩弹性模量提高了2.3倍,平台应力提高了1.5倍,由于镍层的存在,泡沫铝在650 ℃以上高温压缩时强度依然存在;镀镍后泡沫铝自腐蚀电位、电蚀电位、致钝电位分别正向移动238、51和220 mV,耐腐蚀性能提高。

 

关键字: 泡沫铝;电镀;结合强度;热震;耐蚀性;压缩

Properties of aluminum foams with electrodeposited Ni coatings
LIU Huan1, YAO Guang-chun1, CAO Zhuo-kun1, HUA Zhong-sheng2, SHI Jian-chao1

1. School of Material and Metallurgy, Northeastern University, Shenyang 110004, China;
2. School of Metallurgy and Resources, Anhui University of Technology, Maanshan, 243002, China

Abstract:Aluminum foams were electroplated Ni coatings to improve its assistance to heat and corrosion. SEM was used to observe the surface topography of the coatings, while the cohesive force between coatings and matrix compress (ambient temperature and above 650 ℃) and neutral electrochemistry corrosion were tested. The results show that the compactness of coatings is in proportion to the current density in a certain field but the oversize conditions (≥3 A/dm2), and the covering ability improves due to the additives. The adhesion between coatings and aluminum foam matrix is good and reaches its maximum value at the current density of 1 A/dm2 and coating thickness of 28−30 µm. The elastic modulus and plateau stress of aluminum foams with Ni coatings are 2.3 and 1.5 times of those without coatings, respectively. Because of Ni coatings, the strength of aluminum foams still exists at temperature above 650 ℃. Ecorr, Epit and Epp of aluminum foams shift 238, 51 and 220 mV towards positive after electroplated, respectively.

 

Key words: aluminum foam; electroplating; bonding force; hot shock; corrosion assistance; compress

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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