Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第22卷    第9期    总第162期    2012年9月

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文章编号:1004-0609(2012)09-2486-06
微量Sn和In对Al-3.5%Cu合金时效行为及微观组织演变的影响
舒 军,陈志国,李世晨,张纪帅,任杰克

(中南大学 材料科学与工程学院,长沙 410083)

摘 要: 通过显微硬度测试和透射电镜观察,研究微量Sn和In对Al-3.5%Cu  (质量分数)合金的时效特性及微观组织演变的影响。结果表明:在Al-3.5%Cu合金中添加少量Sn能加速合金的时效进程并增强合金的时效硬化和强化效果,且复合添加0.15%In和0.15%Sn(质量分数)时合金的时效强化效果优于添加0.3%Sn合金的;微量Sn、In的添加能明显促进Al-3.5%Cu合金中θ′相的析出,并使之细小呈弥散分布;时效早期,Sn′ 粒子和Sn/In′ 粒子先于θ ′相析出,并可作为θ′相非均匀形核位置,从而增加了θ′相的形核率;微量Sn、In的添加能抑制θ′相的粗化,提高合金过时效性能。

 

关键字: 铝合金;Sn;In;时效特性;微观组织

Effect of trace Sn(In) addition on ageing behaviour and microstructure evolution of Al-3.5%Cu alloy
SHU Jun, CHEN Zhi-guo, LI Shi-chen, ZHANG Ji-shuai, REN Jie-ke

School of Materials Science and Engineering, Central South University, Changsha 410083, China

Abstract:The effects of trace Sn and In additions on the ageing behavior and microstructure evolution of Al-3.5%Cu alloy were investigated by the micro-hardness test and TEM. The results indicate that the trace addition of Sn can increase the ageing rate and enhance the effect of ageing hardening and strengthening. Compared with separate addition of 0.3%Sn (mass fraction) alloy, the addition of 0.15%In and 0.15%Sn has more favorable effect on the ageing strengthening. The trace addition of Sn and In to Al-3.5%Cu alloy can promote the precipitation of θ ′ phase, refine the precipitate and improve its distribution. During the initial stages of ageing, the Sn′ and Sn′(In′) particles precipitate earlier than θ ′ phase, which increases the nucleation rate of θ  ′ phase by providing effective heterogeneous nucleation sites for θ′ phase. In addition, the additions of Sn and In can restrain the coarsening of θ  ′ phase and enhance the age hardening response.

 

Key words: aluminum alloy; Sn; In; aging characteristics; microstructure

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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