Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第20卷    第9期    总第138期    2010年9月

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文章编号:1004-0609(2010)09-1665-06
AZ31B镁合金表面激光熔覆Cu-Ni合金层
崔泽琴1, 2, 吴宏亮1, 王文先1, 2, 许并社1, 2

(1. 太原理工大学 材料科学与工程学院,太原 030024;
2. 太原理工大学 新材料界面科学与工程教育部重点实验室,太原 030024
)

摘 要: 针对镁合金表面耐磨性和耐蚀性差的问题,利用横流CO2激光器在AZ31B镁合金表面激光熔覆Cu-Ni合金层,并利用光学显微镜(OM)、扫描电镜(SEM)和能谱分析仪(EDS)分析熔覆层与基体的结合界面特征以及显微组织和成分分布情况,测试合金层的显微硬度和耐蚀性。结果表明:合金层与基体结合良好,缺陷较少,但局部存在不均匀的Cu-Ni富集区,且在其边缘区域的枝晶间均匀分布着1~1.5 µm的十字状Laves相;合金层的硬度分布比较均匀,约为75HV0.05,明显高于基体的显微硬度45HV0.05;Cu-Ni合金层比AZ31B镁合金基体的腐蚀电位正移317 mV,腐蚀电流降低78 mA/cm2,耐蚀性也得到较大改善。

 

关键字: AZ31B镁合金;Cu-Ni合金层;激光熔覆;耐磨性;耐蚀性

Laser cladding Cu-Ni alloy layer on AZ31B magnesium alloy
CUI Ze-qin1, 2, WU Hong-liang1, WANG Wen-xian1,2, XU Bing-she1,2

1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
 
2. Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education,
Taiyuan University of Technology, Taiyuan 030024, China

Abstract:To improve the wear resistance and corrosion resistance of the surface of magnesium alloy, the laser alloying experiment was carried out on the AZ31B magnesium alloy with pre-placed Cu-Ni powder using transverse flow CO2 laser. The microstructures, interface features and composition distribution of laser cladding layer were studied through OM, SEM and EDS. The results show that the Cu-Ni cladding layer and the substrate achieve a good metallurgical bonding without obvious defects. But there is uneven local Cu-Ni-rich region, and cross-like Laves phases with size of 1−1.5 μm evenly distribute between dendrites and in their edge regions. The microhardness of Cu-Ni cladding layer is more evenly distributed, about 75HV0.05, significantly higher than the matrix hardness (45HV0.05). Compared with AZ31B magnesium alloy, the corrosion potential of Cu-Ni alloy layer is shifted by 317 mV and corrosion current is reduced by 78 mA/cm2.

 

Key words: AZ31B magnesium alloy; Cu-Ni alloy layer; laser cladding; wear resistance; corrosion resistance

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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