文章编号：(1996)03-46-4
PbSiF6-H2SiF6体系电沉积铅的电化学①
(湖南大学环境保护研究所，长沙410082)
摘 要: 采用动电位法研究了在PbSiF6-H2SiF6电解液体系中，添加剂及工艺参数对电沉积Pb阴极过程的影响，探讨了电沉积Pb，过程的电化学反应机理。研究结果表明，控制电解液含Pb量为40~120g/L，H2SiF6为90~120 g/L，添加剂木质磺酸钠为4g/L时，可以获得高质量的Pb沉积物。
关键字: Pb H2SiF6 电沉积
ELECTROCHEMISTRY OF ELECTRODEPOSITING
Pb IN PbSiF6-H2SiF6SYSTEM
Pb IN PbSiF6-H2SiF6SYSTEM
（Institute for Environmental Protection, Hunan University, Changsha 410082）
Abstract:The influence of additive and technological parameter on cathode process of electrodepositing Pb in PbSiF6-H2SiF6electrolytic system was investigated by motional electric potential. The electrochemical mechanism of the process is indicated. The experimental results showed that controlling Pb in electrolyte as 40~120 g/L,H2SiF6as 90~120 g/L, sodium wood-sulfonate additive as 4 gL, high quality deposit Pb was obtained.
Key words: Pb H2SiF6 electrodeposition
