Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第7卷    第4期    总第25期    1997年12月

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文章编号:(1997)04-38-4
含锌铅粉尘配碳球团中铅挥发动力学
王东彦1   王文忠1      陈伟庆   周荣章2    林宗彩 2

(1.东北大学钢铁冶金系, 沈阳 110006;
2.北京科技大学冶金系, 北京 100083
)

摘 要: 在氮气气氛和1100~1300℃温度范围内, 对含锌铅粉尘配碳球团中的铅挥发动力学的研究表明。还原温度对铅挥发速率有显著影响,而煤粉粒度及过量碳含量对铅挥发速度则没有影响。求得铅挥发表观活化能为88.74 kJ/mol,并确定铅的挥发限制性环节为铅的蒸发和铅通过其表面气相边界层的扩散。

 

关键字:      锌铅粉尘    配碳球团    挥发动力学

EVAPORATION KINETICS OF LEAD IN CARBON-CONTAINING PELLETS FROM Zn-Pb-BEARING DUSTS
Wang Dongyan1, Wang Wenzhong1,Chen Weiqing2, Zhou Rongzhang2, Lin Zongcai2

1.P.O.BOX 3137, Northeastern University, Shenyang 110006
2.University of Science & Technology Beijing, Beijing 100083

Abstract:The study on the evaporation kinetics of lead in carbon-containing pellets made of Zn-Pb-bearing dusts, in an nitrogen atmosphere and between 1100℃ and 1300 ℃, showed that the reduction temperature has significant effects on evaporation rate of lead and that the particle size of coal powder and the extra carbon content have not effects on the evaporation rates. The activation energy 88.74kJ/mol was calculated for lead evaporation. The rate of lead evaporation is controlled by the lead volatilization reaction and the diffusion of gaseous lead through gas boundary on surface of the liquid lead.

 

Key words:     Zn-Pb-bearing dusts    carbon-containing pellets    evaporation kinetics

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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