文章编号：(1997)01-49-3
Cu2(ASA)4 配合物的电子光谱
(1.昆明贵金属研究所，昆明 650221;
2.昆明医学院， 昆明 650031)
摘 要: 采用紫外/可见分光光谱法,结合其他分析技术，研究了 tetrakis-[μ-acetylsalicylato-O1O2]dicopper(Ⅱ)(简称Cu2(ASA)4)配合物的电子光谱。实验结果表明，该配合物有三种类型特征吸收谱带，分别归属为2Eg→2T2gd-d 电子跃迁，Cu→Cu d-d 电子迁移和RCOO→Cu的电荷转移。
关键字: 乙酰水杨酸 铜配合物 电子光谱
ELECTRONIC SPECTRA OF TETRAKIS- [μ-ACETYLSALICYLATO-O1O2] DICOPPER(Ⅱ) COMPLEX
（1.Kunming Institute of Precious Metals, Kunming 650221
2.Kunming Medical College, Kunming 650031）
Abstract:The spectra of tetrakis-[μ-acetylsalicylato-O1O2] dicopper(Ⅱ) complex were studied by using ultra-visible spectrum , combined with other analytical techniques. The results showed that the complex has three kinds of absorption bands, which are 2Eg→2T2gd-d transition, Cu→Cu d-d shift and RCOO→Cu charge transfer.
Key words: acetylsalicylate copper(Ⅱ) complex electronic spectrum
