Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第13卷    第2期    总第53期    2003年4月

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文章编号:1004-0609(2003)02-0517-05
未活化与机械活化闪锌矿的氧化行为
胡慧萍, 陈启元, 尹周澜, 张平民, 叶露升, 郭冠华

(中南大学 化学化工学院, 长沙 410083)

摘 要: 用TG分析法研究了未活化与机械活化闪锌矿在氧气氛下的氧化行为, 结果表明,在400~873K之间, 机械活化闪锌矿的剩余质量随着球磨时间的增加而增加,未活化闪锌矿则表现为热质量损失。 用粒度分析、 X射线衍射分析和重量分析法分别对机械活化闪锌矿的结构进行了表征。 发现随着球磨时间的增加,机械活化闪锌矿球磨一定时间后, 其比表面积基本保持不变, 而晶格畸变率增大, 晶块尺寸降低, 且机械活化闪锌矿中的单质硫磺含量极低, 可忽略不计。 机械活化和未活化闪锌矿在TG曲线上的表现主要与晶格畸变率增大和晶块尺寸降低有关。 

 

关键字: TG分析法; 氧化行为; 闪锌矿; 机械活化; 晶格畸变

Oxidation behaviors of unactivated and  mechanically activated sphalerite
HU Hui-ping, CHEN Qi-yuan, YIN Zhou-lan, ZHANG Ping-min, 
YE Lu-sheng, GUO Guan-hua

College of Chemistry and Chemical Engineering,
 Central South University, Changsha 410083, China

Abstract:The oxidation behaviors of unactivated and mechanically activated sphalerite were investigated using thermogravimetry (TG) in oxygen. It is found that the remaining mass at 400~873K in TG curves rises with increasing the grinding time. The surface structures were characterized by laser particle size analysis, X-ray powder diffraction analysis (XRD) and gravimetric method, respectively. The specific surface area of mechanically activated sphalerites remains almost constant after a certain grinding period, and the content of elemental sulphur of mechanically activated sphalerite is determined as 5×10-4,and the lattice distortion increases, but the crystallite size decreases with increasing the grinding time. All the results imply that the mass increase at 400~850K in the TG curve of mechanically activated sphalerite depends mainly on the increase of lattice distortion and the decrease of crystallite size with increasing grinding time.

 

Key words: thermogravimetry; oxidation behavior; sphalerite; mechanical activation; lattice distortion

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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