(中南大学 冶金科学与工程学院,长沙 410083)
摘 要: 提出了一种分子设计和定向寻找分离试剂的新方法。 以相似元素钨和钼的分离为例, 根据WO42-和MoS42-的结构特征, 从价键因素、 亲水-疏水因素、几何因素等方面分析了它们与吸附剂的作用, 成功选择了有色金属硫化物作为选择性吸附剂, 实现钨和钼的高效分离, 并进一步探讨了吸附剂的改性优化和其它类似元素的深度分离问题。
关键字: 相似元素分离; 分子设计; 钨冶金; 吸附剂
(School of Metallurgical Science and Engineering, Central South University,
Changsha 410083, China)
Abstract:A novel method is developed for designing and/or directional searching the reagents using in separation of resemble elements.According to the differences in chemical and structural characters of WO42- and MoS42- the actions of them to separator molecular such as bonding, hydrophile/hydrophobia and geometry are discussed by using mineral flotation as reference.Metal sulfides are chosen for separation of W and Mo. Besides, the optimization of process and the extending to separation of other elements are discussed.Practice shows that novel theory is effective.
Key words: separation of resemble elements; molecular design; tungsten metallurgy; adsorbing agent