Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第12卷    第3期    总第48期    2002年6月

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文章编号:1004-0609(2002)03-0619-05
锌铝铬膜的防腐性能与机理
韩树民,郑炀曾,于升学,徐军明

(燕山大学 材料科学与化学工程学院, 秦皇岛 066004)

摘 要: 通过SEM,XRD,EDS,盐腐蚀试验,热腐蚀试验和电化学测试等研究了锌铝铬膜的防腐蚀性能与机理。结果表明,该膜层耐中性盐腐蚀性能至少优于镀锌钝化层4倍。至于锌铝铬膜层的抗腐蚀机理可能在于锌和铝粒子的电化学保护、铬的表面钝化和锌铝铬化合物保护层的屏蔽等作用,3者的协同作用结果赋予该膜层优异的耐腐蚀性能。

 

关键词: 锌铝铬膜;达克罗;防腐性能;防腐机理

Corrosion prevention
 characteristics and mechanism of
zinc-aluminum-chromium coating
HAN Shu-min,ZHENG Yang-zeng,YU Sheng-xue,XU Jun-ming

College of Materials Science and Chemical Engineering,
 Yanshan University,Qinhuangdao 066004, China

Abstract:The anti-corrosion characteristics and mechanism of zinc-aluminum-chromium coating were studied by tests of salt immersion,salt spray and heat treatment test,and by examinations of electro-chemical impedance spectra,SEM,XRD and EDS. The results show that the coating is superior to electro-zinc plating in anti-corrosion. The corrosion prevention mechanism of zinc-aluminum-chromium coating may come from the controlled galvanic protection of zinc and aluminum particles,the passivation of the object surface by chromic acid,and the barrier effect of zinc,aluminum and chromium compound. The combination of the above effects provides superior anti-corrosion characteristics.

 

Key words: zinc-aluminum-chromium coating; Dacromet; anti-corrosion characteristics; corrosion protection mechanism

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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