Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第11卷    第1期    总第40期    2001年2月

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文章编号:1004-0609(2001)01-0068-06
深过冷条件下Cu-Co合金的液相分解
孙占波, 宋晓平, 胡柱东, 杨 森,曹崇德, 魏炳波

(1. 西安交通大学 理学院材料物理系, 西安 710049;
2.西北工业大学 物理系, 西安 710072
)

摘 要: 用金相分析法对含10%~30%Co-Cu合金液态深过冷条件下的液相分解行为进行了研究。结果表明,在深过冷条件下Cu-Co合金首先形成富Co的α枝晶;由于α-Co 枝晶的分数小于平衡凝固态,剩余液相是过饱和的;当液态合金过冷到液相分解区后,将分解成富Cu和富Co的两个液相。Cu-Co合金液相分解过程包括富Co液滴的形成、长大、积聚及富Co液滴的二次相分解。首次观察到在过饱和的富Cu液相发生液相分解后,原始枝晶重熔并参与液相分解的反常现象。

 

关键字: 深过冷; 液相分解; Cu-Co合金; 金相组织

Liquid separating behavior of Cu-Co alloys
under deep supercooling
SUN Zhan-bo, SONG Xiao-ping, HU Zhu-dong, YANG Sen
CAO Chong-de, WEI Bing-bo

1. Department of Materials Physics, Faculty of Science, Xi'an Jiaotong Universty,
Xi′an 710049, P.R.China;
2. Department of Physics, Northwestern Polytechnical University, Xi′an 710072, P.R.China

Abstract:The liquid separation behaviors of 10%~30% Co-Cu alloys were investigated by means of melt glass deep supercooling technology. The results reveal that α-Co dendrites are firstly crystallized under the condition of deep supercooling. Because the fraction of α-Co dendrites is less than that of equilibrium condition, the remnant liquid phase is supersaturated. When temperature is below the liquid separation line, the melt will separate into the Co-rich and Cu-rich liquid phases. Separation process includes formation, growth, collection of liquid drops and coarseness of Co-rich clusters. The abnormal phenomena that the primitive dendrites remelt and participate in liquid separating after supersaturating liquid separation were observed firstly.

 

Key words: deep supercooling; liquid separation; Cu-Co alloy; microstructure

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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