Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第14卷    第1期    总第58期    2004年1月

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文章编号:1004-0609(2004)01-0055-05
Al-Cu合金时效初期的价电子结构
钟夏平, 高英俊, 刘 慧

(广西大学 物理科学与工程技术学院, 南宁 530004 )

摘 要: 用固体经验电子理论(EET)对Al-Cu合金时效初期的析出相的价电子结构进行计算。 计算结果表明: 合金基体析出的共格GP区、 θ″相, 具有比基体更强的共价键络, 提升了合金的整体键络强度。 从价电子结构层次上解释了时效初期的GP区和θ″相对合金强化作用的内在原因。

 

关键字: Al-Cu合金; 析出相; 时效强化; 价电子结构

Valence electronic structures of
Al-Cu alloy in early aging condition
ZHONG Xia-ping, GAO Ying-jun, LIU Hui

School of Physical Science and Technology, Guangxi University, Nanning 530004, China

Abstract: According to the “Empirical Electron Theory in Solid and Molecules”(EET), the valence electronic structures of the precipitations in Al-Cu alloy in early aging condition were calculated. The results show that the covalence bond-net in the GP zone and θ″ phase coherence with bulk were much stronger than that in bulk, and enhanced the whole covalence bond strength of alloy. These can be used to reveal the inside cause of alloy strengthening from valence electron structure levels in early aging.

 

Key words: Al-Cu alloy; precipitates; age-hardening; valence electron structure

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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