( 1. 东北大学 理学院, 沈阳 110004；
2. 山东理工大学 化工学院, 淄博 255049)
摘 要: 采用基于Pechini法的低温燃烧工艺制备了SrCe0.95Y0.05O3-x(SCY)前驱物。 前驱物在900 ℃经0.5h的煅烧处理即可得到纯的粒度在7～25 nm范围内的SrCe0.95Y0.05O3-x固体电解质纳米粉。 将煅烧的粉体在18 MPa压力下压成片状的素坯， 在900～1 500 ℃的温度范围内于空气中烧结素坯10 h。 用X射线衍射(XRD)表征煅烧粉体的晶体结构， 用扫描电镜(SEM)和透射电镜(TEM)表征了煅烧粉体和烧结体的形貌和粒度， 采用阿基米德法测量了烧结体的密度。 结果表明： 温度达到1 000 ℃时， 烧结体的径向收缩率和密度随着温度的升高而显著增加； 温度达1 300 ℃时烧结体的径向收缩率和密度趋于恒定， 得到相对密度高于96％、 平均粒径约为3.68μm 的SrCe0.95Y0.05O3-x固体电解质陶瓷体。
关键字: 固体电解质； SrCe0.95Y0.05O3-x； 纳米陶瓷粉； 烧结；低温燃烧
（ 1. College of Science, Northeastern University,
Shenyang 110004, China;
2. College of Chemical Engineering and Technology,
Shandong University of Technology, Zibo 255049, China）
Abstract: Precursors for SrCe0.95Y0.05O3-x (SCY) were synthesized by sol-combustion process based on the Pechini method. Pure SrCe0.95Y0.05O3-x nanosized powders with the size range of 7-25 nm were obtained after calcining the precursors at 900 ℃ for 0.5 h. The calcined powders were pressed into pellets at 18 MPa. These pellets were sintered at the temperature range of 900-1500 ℃ for 10h in air. The crystal structure of the calcined powders was analyzed using XRD. The morphology and crystallite sizes of the calcined powders and the sintered pellets were observed using SEM and TEM. The densities of the sintered pellets were measured using Archimedes method with water. The results indicate that, at 1 000 ℃ and above, the radial shrinkage and the density of the sintered pellets obviously increase; at a temperature as high as 1 300 ℃, nearly fully dense SrCe0.95Y0.05O3-x ceramic (relative density larger than 96%) with a mean grain size of 3.68 μm can be obtained.
Key words: solid electrolyte; SrCe0.95Y0.05O3-x; nanosized ceramic powder; sintering; low temperature combustion
