Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第16卷    第9期    总第90期    2006年9月

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文章编号: 1004-0609(2006)09-1647-06
硫酸盐还原菌与单质铁协同作用处理酸性含锌废水
常晓雷, 康 勇, 冯 颖

(天津大学 化工学院, 天津 300072)

摘 要:  研究利用硫酸盐还原菌(sulfate reducing bacteria, SRB)与单质铁协同作用处理含Zn2+废水的效果和相应机理。 采用间歇式生物反应器, 在Zn2+名义浓度为0~90 mg/L范围内, 分别考察SRB和SRB+Fe0两种体系的处理效果。 实验表明: SRB+Fe0体系的处理效果明显优于SRB体系; 加入单质铁之后, 高Zn2+浓度下(>75 mg/L)SRB适应期缩短20%以上; Zn2+对SRB的抑制浓度提高约20%; 硫酸盐还原速率明显加快, 硫酸盐最终还原率以及Zn2+的去除速率都有所提高。 分析了单质铁对废水处理过程的强化机理, 确定Zn2+的去除形式主要为硫化物沉淀。

 

关键字:  单质铁; 酸性含锌废水; 硫酸盐还原菌

Treatment of acid zinc wastewater by sulfate reducing bacteria cooperated with iron
CHANG Xiao-lei, KANG Yong, FENG Ying

School of Chemical Engineering and Technology, Tianjin University, 
Tianjin 300072, China

Abstract: The treatment of wastewater containing Zn2+ by sulfate reducing bacteria cooperated with Fe0 was studied. Two systems of SRB and SRB+Fe0 were experimented in batch bioreactor, with Zn2+ concentration in the range of 0-90 mg/L. The results show that the SRB+Fe0 system performs much better than SRB system. With the presence of iron, the acclimation period of SRB reduces more than 20% under high Zn2+ concentration; the inhibiting concentration of Zn2+ to SRB increases by approximately 20%; the reduction velocity of sulfate is fastened apparently, meanwhile the ultimate sulfate reduction rate and Zn2+ removal rate are improved to a certain extent. The enhancement principle of iron was analyzed and it is concluded that the removal of Zn2+ is mainly in terms of sulfide precipitate.

 

Key words: iron; acid zinc wastewater; sulfate reducing bacteria

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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