(燕山大学 亚稳材料科学与技术国家重点实验室，秦皇岛 066004)
摘 要: 采用X射线衍射技术测定了Inconel 718合金中δ相在980、 1 000和1 020 ℃时的溶解动力学， 并采用扫描电镜进行了组织观察。 结果表明： Inconel 718合金在980、 1 000和1 020 ℃保温过程中， δ相含量逐渐降低， 经1 020 ℃保温2 h后， δ相可完全溶入基体； 当温度为980和1 000 ℃时， δ相的平衡含量分别约为3%及0.6%。 δ相的溶解过程可分为两个阶段， 溶解初期主要表现为长针状δ相长度方向的断裂，且很快溶解断裂为短棒状及颗粒状， 同时在厚度方向上尺寸逐渐减小； 随着溶解过程的进行， 后续的溶解过程主要为短棒状及颗粒状δ相尺寸的减小。 δ相溶解动力学过程的控制环节并非Nb或Ni原子的长程扩散过程， 而为δ相分解的界面反应过程。
关键字: Inconel 718合金； 溶解动力学； 控制环节；扩散； 界面反应
inconel 718 alloy
（State Key Laboratory of Metastable Materials Science and Technology,
Yanshan University, Qinhuangdao 066004, China）
Abstract: The dissolution kinetics and microstructures evolution of δ phase in Inconel 718 alloy during holding at 980, 1 000 and 1 020 ℃ were analyzed using X-ray diffraction and scanning electron microscopy. The results indicate that the dynamic equilibrium state reaches after holding at 980 ℃ for more than 30 min and at 1 000 ℃ for more than 2 h, the equilibrium contents are 3.0% and 0.6%, respectively. Nearly, the δ phase dissolves into the austenitic matrix holding at 1 020 ℃ for more than 1 h. The dissolution process of needle-like δ phase can be divided into two stages, the initial stage is mainly characterized as the fracture from long needle shape to short bars or particles. Then, the size of δ phase with short bars or particles decrease at the following stage. The dissolution models of δ phase were established and the controlling step was revealed. The whole dissolution process is governed by the interface reaction mechanism, but not by the long-distance diffusion of Nb or Ni atoms in the austenite matrix.
Key words: Inconel 718 alloy; dissolution kinetics; controlling step; diffusion; interface reaction
