Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第19卷    第3期    总第120期    2009年3月

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文章编号:1004-0609(2009)03-0433-06
双辊铸轧AZ31镁合金板坯的物相分析
唐  宁1,汪明朴1,娄花芬1, 2,李  周1,郭明星1,雷  前1

(1. 中南大学 材料科学与工程学院,长沙 410083;
2. 中铝洛阳铜业有限公司,洛阳 471039
)

摘 要: 采用双辊铸轧技术制备AZ31镁合金板坯,利用X射线衍射、金相显微镜、扫描电子显微镜以及能谱分析等技术对该板坯的物相进行分析。结果表明: 双辊铸轧AZ31镁合金板坯中的物相主要有α-Mg枝晶、枝晶间富溶质α-Mg和不规则的块状Mg17(Al, Zn)12相组成的离异共晶以及弥散分布于晶内的星形细小Al8Mn5相;在双辊铸轧过程中,随着Mg液温度的降低,过饱和的Mn以Al8Mn5相的形式从Mg液中析出,而后细小的Al8Mn5相随着α-Mg初晶的长大进入枝晶胞内部;α-Mg初晶长大的同时,Al、Zn等元素在枝晶间未凝固的液相中富集,最终在枝晶间形成依附于初晶的富溶质α-Mg和不规则的块状Mg17(Al, Zn)12相组成的离异共晶。

 

关键字: AZ31镁合金;双辊铸轧;物相

Phases analysis of twin-roll casting AZ31 Mg alloy
plate blank
TANG Ning1, WANG Ming-pu1, LOU Hua-fen1, 2, LI Zhou1, GUO Ming-xing1, LEI Qian1

1. School of Materials Science and Engineering, Central South University, Changsha 410083, China;
2. CHINALCO Luoyang Copper Co. Ltd., Luoyang 471039, China

Abstract: AZ31 Mg alloy plate was fabricated successfully by twin-roll casting technology, and the phases in the plate were analyzed by X-ray diffraction, metallographic microscope, scanning electron micrograph and an energy dispersion X-ray spectroscopy. The results show that the phases of twin-roll casting AZ31 Mg alloy are composed of α-Mg dendritic, divorced eutectic with α-Mg and irregular massive Mg17(Al, Zn)12, and fine star-shaped Al8Mn5. During the twin-roll casting process, the supersaturated Mn precipitates from the melt in the form of Al8Mn5 phases, and then the little Al8Mn5 phases enter into the dendritic with the α-Mg primary crystals growing up with temperature decreasing. At the same time, Al and Zn enrich in the remaining melt between dendritics, which leading to the formation of the divorced eutectic composed of enriched α-Mg leeching on the primary crystal and irregular massive Mg17(Al, Zn)12 phases in the interdendritic.

 

Key words: AZ31 Mg alloy; twin-roll casting; phase

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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